The Aufbau principle says electrons fill the lowest available energy sub-shells first. You do not randomly place electrons. You follow an energy order such as 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, and so on. That order explains why potassium puts its outer electron in 4s, not 3d.
⬆️ AUFBAU
Aufbau means building up: fill lowest energy orbitals before higher ones.