Look at chlorine on the periodic table and you will not see a neat whole number. Relative atomic mass, Ar, is a weighted average of the masses of an element's naturally occurring isotopes. Chlorine is mostly chlorine-35 with some chlorine-37, so the average sits near 35.5.
📊 Ar
Relative atomic mass is the average mass of atoms of an element compared with one twelfth of the mass of a carbon-12 atom.